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Inconel 625-316L焊接接头在海水环境中的腐蚀行为研究

Corrosion behavior of Inconel 625-AISI 316L weld joints in seawater environment

  • 摘要: 焊接接头是管道服役过程中腐蚀失效高发的薄弱部位。该文针对Inconel 625合金与316L不锈钢焊接接头,研究其在海水浸泡环境下的腐蚀行为,以深化对该类接头腐蚀特性与作用机制的认知。对Inconel 625-316L焊接接头开展海水浸泡腐蚀试验,腐蚀周期结束后,采用扫描电子显微镜(SEM)观测腐蚀表面的微观形貌,结合能量色散X射线光谱(EDS)分析腐蚀表面的元素组成与产物特征,从微观层面揭示接头的腐蚀演化规律。焊接接头的整体腐蚀速率显著高于单一316L不锈钢,在焊缝附近316L区域有大量深的蚀坑,随着距焊缝距离增加,蚀坑数量和深度都有明显下降。随着腐蚀时间增加,腐蚀表面含氧量明显增多,说明氧化产物增多。海水环境下Inconel 625与316L的焊接接头会发生显著电偶腐蚀,氧化产物的累积是腐蚀进程推进的重要微观表现,该研究结果可为海底长输管道焊接接头的腐蚀防控设计与寿命评估提供试验依据。

     

    Abstract: Welded joints are vulnerable sections with high incidence of corrosion failure during pipeline service. This paper studies the corrosion behavior of welded joints between Inconel 625 alloy and 316L stainless steel under seawater immersion, so as to deepen the understanding of the corrosion characteristics and action mechanism of such joints. Seawater immersion corrosion tests were carried out on Inconel 625-316L welded joints. After corrosion period, scanning electron microscopy (SEM) is used to observe the micromorphology of the corroded surface, and energy dispersive X-ray spectroscopy (EDS) is applied to analyze the elemental composition and product characteristics of the corroded surface, in order to reveal the corrosion evolution law of the joints at the micro level. The overall corrosion rate of the welded joints is significantly higher than that of monolithic 316L stainless steel. A large number of deep corrosion pits are present in the 316L region near the weld seam, and both the number and depth of corrosion pits decrease remarkably with increasing distance from the weld seam. With the increasing of corrosion time, the oxygen content on the corroded surface rises significantly, indicating an increase in oxidation products. Significant galvanic corrosion occurs in the welded joints of Inconel 625 and 316L in seawater environment, and the accumulation of oxidation products is an important microscopic manifestation of corrosion progression. The findings of this study can provide a test basis for corrosion prevention design and life evaluation of welded joints in subsea long-distance pipelines.

     

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