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碳酸盐岩酸蚀规律及微观孔隙结构改造特征

The acid etched law of carbonate rocks and modification characteristics of microscopic pore structures

  • 摘要: 酸化酸压是伊拉克F油田碳酸盐岩油藏增产的主要技术手段。为了提高该油田酸化酸压措施效果,厘清酸蚀规律及微观孔隙结构的改造特征,采用X-射线衍射、电镜扫描、薄片分析、CT成像等实验方法对F油田碳酸盐岩酸蚀规律及孔隙结构的改造特征进行了研究。实验结果表明:① 酸蚀仅对成分和晶体有选择性,对基质和孔隙不具有选择性;盐酸优先溶蚀方解石,晶体大的方解石比晶体小的方解石更易溶蚀,晶体小的白云石比晶体大的白云石更易溶蚀;② 酸蚀明显增加储集空间,纯的灰岩或白云岩会形成大的溶洞,灰质和白云质混合则会形成连片的溶孔,砂质云岩会形成石英颗粒间溶孔;③ 原始孔隙发育的储层在与盐酸接触的岩石表面形成大的溶洞和多条垂直于表面的裂缝,明显增加了储集空间和渗流通道;原始孔隙不发育的储层仅在与盐酸接触的岩石表面形成大的溶洞或少量蚓孔,深部沟通较差。实验结果为伊拉克F油田酸化酸压方案优化设计提供了理论指导。

     

    Abstract: Acidizing and acid fracturing are main technical measures for increasing production of Oilfield F in Iraq. To improve the effectiveness of these measures, clarify the rules of acid etched and modification characteristics of microscopic pore structures, this study uses experimental methods such as X-ray diffraction, scanning electron microscopy (SEM), thin section analysis and CT imaging to study the acid etched rules and microscopic pore structures modification characteristics of carbonate rocks in Oilfield F.The experimental results show that: ① Acid etching exhibits selectivity only for minerals and crystals, not for matrix or pores. Hydrochloric acid preferentially dissolves calcite, and calcite with large crystals is more prone to dissolution than calcite with small crystals. Dolomite with small crystals is more prone to dissolution than dolomite with large crystals. ② Acid erosion significantly increases storage space, and pure limestone or dolomite forms large karst caves. Limestone-dolomite mixtures develop connected dissolved pores and sandy dolomite generates intergranular dissolved pores around quartz particles. ③ Reservoirs with well-developed primary pores form large vugs and multiple surface-perpendicular fractures on the rock surface in contact with hydrochloric acid, significantly increasing the storage space and seepage channels. Reservoirs with undeveloped primary pores only form large karst caves or a small number of wormholes on the surface of rocks, resulting in poor deep connectivity. The experimental results provide theoretical guidance for the optimization design of acidizing and acid-fracturing in Oilfield F in Iraq.

     

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