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孙鹏宵, 徐国瑞, 刘文辉, 张云宝, 薛宝庆, 陈欣. Cr3+与聚合物在岩心内静态成胶效果评价[J]. 海洋石油, 2014, 34(4): 53-58. DOI: 10.3969/j.issn.1008-2336.2014.04.053
引用本文: 孙鹏宵, 徐国瑞, 刘文辉, 张云宝, 薛宝庆, 陈欣. Cr3+与聚合物在岩心内静态成胶效果评价[J]. 海洋石油, 2014, 34(4): 53-58. DOI: 10.3969/j.issn.1008-2336.2014.04.053
SUN Pengxiao, XU Guorui, LIU Wenhui, ZANG Yunbao, XUE Baoqing, CHEN Xin. Evaluation on the Static Gelling Effects of Cr3+ and Polymer within Cores[J]. Offshore oil, 2014, 34(4): 53-58. DOI: 10.3969/j.issn.1008-2336.2014.04.053
Citation: SUN Pengxiao, XU Guorui, LIU Wenhui, ZANG Yunbao, XUE Baoqing, CHEN Xin. Evaluation on the Static Gelling Effects of Cr3+ and Polymer within Cores[J]. Offshore oil, 2014, 34(4): 53-58. DOI: 10.3969/j.issn.1008-2336.2014.04.053

Cr3+与聚合物在岩心内静态成胶效果评价

Evaluation on the Static Gelling Effects of Cr3+ and Polymer within Cores

  • 摘要: 近年来,在SZ36-1和LD10-1油田开展了聚合物驱和聚合物凝胶调驱矿场试验,取得了明显增油降水效果,为海上油田提高采收率找到了一条有效途径,但油藏中的各种复杂环境和条件可能会对其交联反应存在影响。通过理论分析和物理模拟实验,开展了交联剂Cr3+与聚合物在岩心内静态成胶效果评价实验研究。结果表明,在静态条件下,交联剂Cr3+与聚合物分子间可以在岩心孔隙内发生交联反应,其成胶效果受到岩心渗透率及其类型(是否含胶结物)、岩心含油饱和度、黏土矿物类型和含量等因素的影响,其中渗透率影响程度较大;随岩心渗透率增大即孔隙尺寸增大,岩心内成胶效果变好;随含油饱和度降低,岩心成胶效果变好;随黏土含量增加,岩心内成胶效果变差,而且在三种岩心黏土类型中,伊利石的影响最大,其次为高岭石,再其次为蒙脱石;岩石颗粒胶结愈疏松,成胶效果愈好。这些研究成果对于国内外油田利用弱凝胶进行深部调剖技术进一步提高开发效果具有指导作用。

     

    Abstract: In recent years, polymer flooding and polymer gel flooding field test have been carried out in SZ36-1 and LD10-1 oil field, with an obvious effect in increasing oil production and decreasing water production, finding an effective way to enhance oil recovery for offshore oil field. However, various complex environments and conditions in the reservoir may influence the crosslinking reaction. In this paper, experiment of the static gelling results of the crosslinking agent Cr3+ and polymer within core has been carried out through theoretical analysis and physical simulation experiment. The study results indicated that under the condition of static, cross-linking reaction between crosslinking agent Cr3+ and polymer molecules can occurs in the pores of core, and its gelling effect is influenced by core permeability and its type (whether including cement), core oil saturation, clay minerals type and content, and the influence degree of permeability is the largest. With the increase of core permeability, namely increasing in pore sizes, the gelling effect gets better in the core. With decreasing in oil saturation, the gelling effect gets better in the core. With increasing in clay content, the gelling effect gets worser in the core. Among the three core clay types, the effect of illite is biggest, followed by kaolinite, then followed by montmorillonite. The more loose of rock particles cemented, the better the gelling effect gets. These results have a guiding role for deep profile technology to improve development effect with weak gel in domestic and international oil fields.

     

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